Difference between revisions of "User:Tohline/SR/EOS"

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(Create page in which to discuss equations of state)
 
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==Equations of State==
==Equations of State==
===Ideal Gas===


===<span id="EOS:IdealGas">Ideal Gas</span>===
The ideal gas equation of state is referred to as the [http://en.wikipedia.org/wiki/Ideal_gas_law ideal gas law] in Wikipedia.  The Wikipedia discussion points out that, as derived from first principles in statistical mechanics, this "gas law" can most naturally be written in the form,
<div align="center">
<math>P = \biggl( \frac{N}{V} \biggr) kT</math>
</div>
where {{User:Tohline/Math/VAR_Pressure01}}, {{User:Tohline/Math/VAR_Temperature01}} and {{User:Tohline/Math/C_BoltzmannConstant}} are as we have defined them in our accompanying [http://www.vistrails.org/index.php/User:Tohline/Appendix/Variables_templates variables appendix], and the ratio <math>(N/V)</math> specifies the number density of free particles that make up the gas.  The number density of free particles also can be written as a ratio of the mass density, {{User:Tohline/Math/VAR_Density01}}, to the average mass per free particle, <math>\bar{m}</math>, that is, the ideal gas equation of state may be written in the form,
<div align="center">
<math>P = \biggl( \frac{\rho}{\bar{m}} \biggr) kT</math> .
</div>
It is customary in astrophysical discussions to write the average mass per free particle as {{User:Tohline/Math/MP_MeanMolecularWeight}}<math>m_u</math>, that is, as a product of the atomic mass unit, <math>m_u</math> = 1/{{User:Tohline/Math/C_AvogadroConstant}}, and a dimensionless coefficient of order unity referred to as the the mean molecular weight, {{User:Tohline/Math/MP_MeanMolecularWeight}}.  This leads to what we will refer to as,
<div align="center">
<font color="red">Form A</font><br />
of the ideal gas equation of state<br />
{{User:Tohline/Math/EQ_EOSideal0A}} ,
</div>
where the gas constant, {{User:Tohline/Math/C_GasConstant}} <math>\equiv</math> {{User:Tohline/Math/C_BoltzmannConstant}}{{User:Tohline/Math/C_AvogadroConstant}}.






{{LSU_HBook_footer}}
{{LSU_HBook_footer}}

Latest revision as of 07:06, 24 January 2010

Whitworth's (1981) Isothermal Free-Energy Surface
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Equations of State

Ideal Gas

The ideal gas equation of state is referred to as the ideal gas law in Wikipedia. The Wikipedia discussion points out that, as derived from first principles in statistical mechanics, this "gas law" can most naturally be written in the form,

<math>P = \biggl( \frac{N}{V} \biggr) kT</math>

where <math>~P</math>, <math>~T</math> and <math>~k</math> are as we have defined them in our accompanying variables appendix, and the ratio <math>(N/V)</math> specifies the number density of free particles that make up the gas. The number density of free particles also can be written as a ratio of the mass density, <math>~\rho</math>, to the average mass per free particle, <math>\bar{m}</math>, that is, the ideal gas equation of state may be written in the form,

<math>P = \biggl( \frac{\rho}{\bar{m}} \biggr) kT</math> .

It is customary in astrophysical discussions to write the average mass per free particle as <math>~\bar{\mu}</math><math>m_u</math>, that is, as a product of the atomic mass unit, <math>m_u</math> = 1/<math>~N_A</math>, and a dimensionless coefficient of order unity referred to as the the mean molecular weight, <math>~\bar{\mu}</math>. This leads to what we will refer to as,

Form A
of the ideal gas equation of state

LSU Key.png

<math>~P_\mathrm{gas} = \frac{\Re}{\bar{\mu}} \rho T</math>

,

where the gas constant, <math>~\Re</math> <math>\equiv</math> <math>~k</math><math>~N_A</math>.


Whitworth's (1981) Isothermal Free-Energy Surface

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